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鎮ㄥソ锛屾杩庝締鍒扮董搴浕瀛愬競鍫寸恫(w菐ng) 鐧婚寗 | 鍏嶈不(f猫i)娉ㄥ唺

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闁辫畝锛�10812鏅�(sh铆)闁擄細2018-06-26 11:22:25

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銆�銆�鍩洪牷宄�(n0鈫�1)2885.9cm鏈�寮�(qi谩ng)
銆�銆�浜屽�嶉牷宄�(n0鈫�2)5668.0cm杓冨急
銆�銆�涓夊�嶉牷宄�(n0鈫�3)8346.9cm寰堝急
銆�銆�鍥涘�嶉牷宄�(n0鈫�4)10923.1cm妤靛急
銆�銆�浜斿�嶉牷宄�(n0鈫�5)13396.5cm妤靛急
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鍩哄湗(tu谩n)闋荤巼

銆�銆�涓磪澶栧厜璀滃崁(q奴)鍙垎鎴�4000 cm~1300(1800) cm鍜�1800 (1300 ) cm~ 600 cm鍏╁��(g猫)鍗�(q奴)鍩熴�傛渶鏈夊垎鏋愬児(ji脿)鍊肩殑鍩哄湗(tu谩n)闋荤巼鍦�4000 cm~ 1300 cm涔嬮枔锛岄�欎竴鍗�(q奴)鍩熺ū鐐哄熀鍦�(tu谩n)闋荤巼鍗�(q奴)銆佸畼鑳藉湗(tu谩n)鍗�(q奴)鎴栫壒寰佸崁(q奴)銆傚崁(q奴)鍏�(n猫i)鐨勫嘲鏄敱浼哥府鎸嫊(d貌ng)鐢�(ch菐n)鐢熺殑鍚告敹甯�锛屾瘮杓冪█鐤忥紝瀹规槗杈ㄨ獚(r猫n)锛屽父鐢ㄤ簬閼掑畾瀹樿兘鍦�(tu谩n)銆�
銆�銆�鍦�1800 cm(1300 cm)~600 cm鍗�(q奴)鍩熷収(n猫i)锛岄櫎鍠嵉鐨勪几绺尟鍕�(d貌ng)澶�锛岄倓鏈夊洜璁婂舰鎸嫊(d貌ng)鐢�(ch菐n)鐢熺殑璀滃付銆傞�欑ó鎸嫊(d貌ng)鍩哄湗(tu谩n)闋荤巼鍜岀壒寰佸惛鏀跺嘲鑸囨暣鍊�(g猫)鍒嗗瓙鐨勭祼(ji茅)妲�(g貌u)鏈夐棞(gu膩n)銆傜暥(d膩ng)鍒嗗瓙绲�(ji茅)妲�(g貌u)绋嶆湁涓嶅悓鏅�(sh铆)锛岃┎鍗�(q奴)鐨勫惛鏀跺氨鏈夌窗(x矛)寰殑宸暟锛屽苟椤ず鍑哄垎瀛愮壒寰�銆傞�欑ó鎯呮硜灏卞儚浜虹殑鎸囩磱涓�妯�锛屽洜姝ょū鐐烘寚绱嬪崁(q奴)銆傛寚绱嬪崁(q奴)灏嶄簬鎸囪獚(r猫n)绲�(ji茅)妲�(g貌u)椤炰技鐨勫寲鍚堢墿寰堟湁骞姪锛岃�屼笖鍙互浣滅偤鍖栧悎鐗╁瓨鍦ㄦ煇绋熀鍦�(tu谩n)鐨勬梺璀�銆�
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銆�銆�(1) 4000 ~2500 cm X-H浼哥府鎸嫊(d貌ng)鍗�(q奴)锛孹鍙互鏄疧銆丯銆丆鎴朣绛夊師瀛�銆�
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銆�銆�鐣�(d膩ng)閱囧拰閰氭憾浜庨潪妤垫�ф憾鍔�(濡侰Cl4)锛屾績搴︿簬0.01mol. dm鏅�(sh铆)锛屽湪3650 ~3580 cm铏曞嚭鐝�(xi脿n)娓搁洟O-H鍩虹殑浼哥府鎸嫊(d貌ng)鍚告敹锛屽嘲褰㈠皷閵�锛屼笖娌掓湁鍏跺畠鍚告敹宄板共鎿�锛屾槗浜庤瓨鍒�銆傜暥(d膩ng)瑭︽ǎ婵冨害澧炲姞鏅�(sh铆)锛岀茎鍩哄寲鍚堢墿鐢�(ch菐n)鐢熺窢鍚堢従(xi脿n)璞�锛孫-H鍩虹殑浼哥府鎸嫊(d貌ng)鍚告敹宄板悜浣庢尝鏁�(sh霉)鏂瑰悜浣嶇Щ锛屽湪3400 ~3200 cm鍑虹従(xi脿n)涓�鍊�(g猫)瀵�屽挤(qi谩ng)鐨勫惛鏀跺嘲銆�
銆�銆�鑳哄拰閰拌兒鐨凬-H浼哥府鎸嫊(d貌ng)涔熷嚭鐝�(xi脿n)鍦�3500~3100 cm锛屽洜姝�锛屽彲鑳芥渻(hu矛)灏峅-H浼哥府鎸嫊(d貌ng)鏈夊共鎿�銆�
銆�銆�C-H鐨勪几绺尟鍕�(d貌ng)鍙垎鐐洪＝鍜屽拰涓嶉＝鍜岀殑鍏╃ó锛�
銆�銆�椋藉拰鐨凜-H浼哥府鎸嫊(d貌ng)鍑虹従(xi脿n)鍦�3000 cm浠ヤ笅锛岀磩3000~2800 cm锛屽彇浠ｅ熀灏嶅畠鍊戝奖闊垮緢灏�銆傚-CH3鍩虹殑浼哥府鍚告敹鍑虹従(xi脿n)鍦�2960 cm鍜�2876 cm闄勮繎锛汻2CH2鍩虹殑鍚告敹鍦�2930 cm鍜�2850 cm闄勮繎锛汻3CH鍩虹殑鍚告敹鍩哄嚭鐝�(xi脿n)鍦�2890 cm闄勮繎锛屼絾寮�(qi谩ng)搴﹀緢寮�銆�
銆�銆�涓嶉＝鍜岀殑C-H浼哥府鎸嫊(d貌ng)鍑虹従(xi脿n)鍦�3000 cm浠ヤ笂锛屼互姝や締鍒ゅ垾鍖栧悎鐗╀腑鏄惁鍚湁涓嶉＝鍜岀殑C-H閸点��
銆�銆�鑻挵(hu谩n)鐨凜-H閸典几绺尟鍕�(d貌ng)鍑虹従(xi脿n)鍦�3030 cm闄勮繎锛屽畠鐨勭壒寰佹槸寮�(qi谩ng)搴︽瘮椋藉拰鐨凜-H婕块嵉绋嶅急锛屼絾璀滃付姣旇純灏栭姵銆�
銆�銆�涓嶉＝鍜岀殑闆欓嵉=C-H鐨勫惛鏀跺嚭鐝�(xi脿n)鍦�3010~3040 cm鑼冨湇鍏�(n猫i)锛屾湯绔�= CH2鐨勫惛鏀跺嚭鐝�(xi脿n)鍦�3085 cm闄勮繎銆�
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銆�銆�R-CCH鐨勪几绺尟鍕�(d貌ng)鍑虹従(xi脿n)鍦�2100~2140 cm闄勮繎锛�
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銆�銆�-C N鍩虹殑浼哥府鎸嫊(d貌ng)鍦ㄩ潪鍏辫粵鐨勬儏娉佷笅鍑虹従(xi脿n)2240~2260 cm闄勮繎銆傜暥(d膩ng)鑸囦笉椋藉拰閸垫垨鑺抽鏍稿叡杌涙檪(sh铆)锛岃┎宄颁綅绉诲埌2220~2230 cm闄勮繎銆傝嫢鍒嗗瓙涓惈鏈塁銆丠銆丯鍘熷瓙锛�-C N鍩哄惛鏀舵瘮杓冨挤(qi谩ng)鑰屽皷閵�銆傝嫢鍒嗗瓙涓惈鏈塐鍘熷瓙锛屼笖O鍘熷瓙闆�-C N鍩鸿秺杩�锛�-C N鍩虹殑鍚告敹瓒婂急锛岀敋鑷宠瀵熶笉鍒�銆�
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銆�銆�C=O浼哥府鎸嫊(d貌ng)鍑虹従(xi脿n)鍦�1900~1650 cm锛屾槸绱呭鍏夎瓬涓壒寰佺殑涓斿線寰�鏄渶寮�(qi谩ng)鐨勫惛鏀�锛屼互姝ゅ緢瀹规槗鍒ゆ柗閰銆侀啗椤�銆侀吀椤�銆侀叝椤炰互鍙婇吀閰愮瓑鏈夋(j墨)鍖栧悎鐗�銆傞吀閰愮殑缇板熀鍚告敹甯剁敱浜庢尟鍕�(d貌ng)鑰﹀悎鑰屽憟鐝�(xi脿n)闆欏嘲,鑻殑琛嶇敓鐗╃殑娉涢牷璀滃付锛屽嚭鐝�(xi脿n)鍦�2000~1650 cm鑼冨湇锛屾槸C-H闈㈠鍜孋=C闈㈠収(n猫i)璁婂舰鎸嫊(d貌ng)鐨勬硾闋诲惛鏀�锛岄洊鐒跺挤(qi谩ng)搴﹀緢寮�锛屼絾瀹冨�戠殑鍚告敹闈㈣矊鍦ㄨ〃寰佽姵鏍稿彇浠ｉ鍨嬩笂鏈変竴瀹氱殑浣滅敤銆�

鎸囩磱鍗�(q奴)

銆�銆�(1)1800(1300)cm~900cm鍗�(q奴)鍩熸槸C-O銆丆-N銆丆-F銆丆-P銆丆-S銆丳-O銆丼i-O绛夊柈閸电殑浼哥府鎸嫊(d貌ng)鍜孋=S銆丼=O銆丳=O绛夐洐閸电殑浼哥府鎸嫊(d貌ng)鍚告敹銆�
銆�銆�鍏朵腑锛�1375cm鐨勮瓬甯剁偤鐢插熀鐨刣C-H灏嶇ū褰庢洸鎸嫊(d貌ng)锛屽皪璀樺垾鐢插熀鍗佸垎鏈夌敤锛孋-O鐨勪几绺尟鍕�(d貌ng)鍦�1300~1000cm锛屾槸瑭插崁(q奴)鍩熸渶寮�(qi谩ng)鐨勫嘲锛屼篃杓冩槗璀樺垾銆�
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宸叉敹閷勮姊�168755鍊�(g猫)