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鎮ㄥソ锛屾杩庝締鍒扮董搴浕瀛愬競鍫寸恫(w菐ng) 鐧婚寗 | 鍏嶈不(f猫i)娉ㄥ唺(c猫)

鑷哀姘ｉ珨妾㈡脯鍎�
闁辫畝锛�1066鏅�(sh铆)闁擄細2022-05-10 17:40:49

    鑷哀姘ｉ珨妾㈡脯鍎�涓昏鏄敤浜庢娓┖闁撳収(n猫i)鑷哀姘ｉ珨婵冨害鐨勮ō(sh猫)鍌�銆�

鍘熺悊

    鑷哀姘ｉ珨妾㈡脯鍎� 渚嗚嚜寰峰湅瀹夋�濈緟鏂叕鍙稿熀鏈師鐞�

    1.1妾㈡脯鍘熺悊

    鎴戝�戠煡閬撳湴鐞冨ぇ姘ｅ堡涓婃湁涓�灞よ嚟姘у堡锛岀瀛�(xu茅)瀹跺�戝凡缍�(j墨ng)鐧�(f膩)鐝�(xi脿n)鑷哀灞よ兘鍚告敹绱绶�锛岀爺绌惰〃鏄庤嚟姘у儏灏�(du矛)娉㈤暦253.7nm鐨勭传澶栫窔鍏锋湁澶у惛鏀剁郴鏁�(sh霉)锛屽湪姝ゆ尝闀蜂笅绱绶氶�氶亷鑷哀鏈�(hu矛)鐢�(ch菐n)鐢熻“娓�锛岀鍚堣槶娉㈢壒鈥斺�旀瘮鐖惧畾寰嬨�傝┎鏂规硶宸茶缇庡湅绛夊湅瀹朵綔鐐鸿嚟姘ф(bi膩o)婧�(zh菙n)鍒嗘瀽鏂规硶銆傝┎鑷哀妾㈡脯鍎�灏辨槸閲囩敤绱绶氬惛鏀舵硶鐨勫師鐞嗭紝鐢ㄧ┅(w臎n)瀹氱殑绱鐕堝厜婧愮敘(ch菐n)鐢熺传澶栫窔锛岀敤鍏夋尝閬庢烤鍣ㄩ亷婵炬帀鍏跺畠娉㈤暦绱鍏�锛屽彧鍏佽ū娉㈤暦253.7nm閫氶亷銆傜稉(j墨ng)閬庢ǎ鍝佸厜闆诲偝鎰熷櫒锛屽啀缍�(j墨ng)閬庤嚟姘у惛鏀舵睜鍚�锛屽埌閬�(d谩)閲囨ǎ鍏夐浕鍌虫劅鍣�銆傞�氶亷妯ｅ搧鍏夐浕鍌虫劅鍣ㄥ拰閲囨ǎ鍏夐浕鍌虫劅鍣ㄩ浕淇¤櫉(h脿o)姣旇純锛屽啀缍�(j墨ng)閬庢暩(sh霉)瀛�(xu茅)妯″瀷鐨勮▓(j矛)绠楋紝灏辫兘寰楀嚭鑷哀婵冨害澶у皬銆�

    1.2鑷哀姘ｉ珨妾㈡脯鍎�

    婵冨害鏁�(sh霉)瀛�(xu茅)瑷�(j矛)绠楁ā鍨�

    鑷哀婵冨害鏁�(sh霉)瀛�(xu茅)妯″瀷锛堝鍏紡涓�锛夋槸鏍规摎(j霉)Lambert and Beer瀹氬緥鎺ㄥ嚭鐨�銆�

    -ln I/I0

    C = 鈥斺�斺�斺�斺��

    E脳D 锛� 鍏紡涓� 锛�

    锛堟敞閲嬶細C-----鑷哀婵冨害锛屽柈浣峠 /m锛汦------ 甯告暩(sh霉)锛汥-------鑷哀鍚告敹姹犺窛闆�锛�

    I0---------妯ｅ搧闆绘祦锛汭------閲囨ǎ闆绘祦锛�

    鍦ㄩ�欏��(g猫)鑷哀婵冨害瑷�(j矛)绠楀叕寮忎腑锛屽彧瑕佺煡閬撴ǎ鍝侀浕娴�銆侀噰妯ｉ浕娴佸拰鑷哀鍚告敹姹犺窛闆紝閭ｄ箞鎴戝�戝氨鍙互瑷�(j矛)绠楀嚭鑷哀婵冨害澶у皬銆傜敱浜�锛岃嚟姘у惛鏀舵睜鐨勮窛闆㈢殑闄愬埗锛屽ぇ鑷哀婵冨害鍙兘娓埌300 O3 g/m銆�

    1.3闆昏矾鍘熺悊鐨勫(sh铆)鐝�(xi脿n)

    鍩烘湰闆昏矾鐢遍浕婧愰儴鍒�銆佺传澶栫噲鎺у埗銆佺传澶栧厜绶氭ǎ鍝佹娓�佺传澶栧厜绶氶噰妯ｆ娓�锛屽皪(du矛)鏁�(sh霉)鏀惧ぇ鍣↙og100銆佹ā鎿几鍑哄強椤ず鍏ぇ閮ㄥ垎绲勬垚銆�

    闆昏矾鏍稿績閮ㄥ垎灏辨槸鐢ㄥ皪(du矛)鏁�(sh霉)鏀惧ぇ鍣↙og100渚嗗(sh铆)鐝�(xi脿n)鑷哀婵冨害鏁�(sh霉)瀛�(xu茅)妯″瀷銆侺OG100鏄� 14寮曡叧鍙互灏�(du矛)鍏╁��(g猫)闆绘祦鎴栭浕澹撲箣姣旈��(j矛n)琛屽皪(du矛)鏁�(sh霉)閬�(y霉n)绠楃殑闆嗘垚闆昏矾锛岃┎鏀惧ぇ鍣ㄨ几鍑洪浕娴佸嫊(d貌ng)鎱�(t脿i)鑼冨湇瀵�锛屽彲浠ュ湪1nA鍒� 1mA涔嬮枔璁婂寲銆傝几鍑鸿宸寖鍦嶄笉0.1%?锛涱姠绐樻吵鈧紙濡傚湒1锛� 锛岃几鍑哄叕寮忥細 Vout =VT脳ln I0/I (娉ㄩ噵锛歏T---甯告暩(sh霉)锛沄out---杓稿嚭闆诲)銆�

    闆绘簮閮ㄥ垎涓昏鏄敘(ch菐n)鐢熺传澶栫噲闇�瑕佺殑楂樺闆绘簮锛屽悓鏅�(sh铆)鐢�(ch菐n)鐢熼浕璺澘涓婇渶瑕佺殑+15V鐩存祦闆�銆傜传澶栫噲鐕堟帶閮ㄥ垎涓昏鏄帶鍒剁传澶栫噲鐕堥浕娴佸湪鎭掑畾鍏佽ū鑼冨湇涔嬪収(n猫i)锛岄亷楂�銆侀亷浣庡彲浠ヨ嚜鍕�(d貌ng)瑾�(di脿o)绡�(ji茅)锛屽鏋滆(di脿o)涓嶄簡瑾槑绱鐕堝＝鍛藉埌浜�锛岄潰鏉夸笂鏈変竴鍊�(g猫)绱呯噲璁婁寒锛屾彁绀轰綘鎳�(y墨ng)瑭叉洿鎻涙柊鐨勭传澶栫噲浜�銆傛(bi膩o)婧�(zh菙n)绱鍏夋娓拰閲囨ǎ绱鍏夋娓儴鍒嗕篃鏄純闂�(gu膩n)閸甸儴鍒�锛�.鍏夐浕鍌虫劅鍣ㄦ妸绱绶氱殑鍏変俊铏�(h脿o)杞�(zhu菐n)鎻涚偤闆诲淇¤櫉(h脿o)锛岀劧鍚庣稉(j墨ng)鍏╂閬�(y霉n)绠楁斁澶у櫒閫�(j矛n)琛屼俊铏�(h脿o)鏁寸悊鏀惧ぇ锛岄�佺郸LOG100閫�(j矛n)琛岃▓(j矛)绠楄檿鐞嗗悗锛岄’绀鸿几鍑�銆傛ā鎿几鍑�0~20mA鑸囪嚟姘ф績搴﹀ぇ灏忔槸鎴愮窔鎬ч棞(gu膩n)绯荤殑銆�


鍩烘湰绲�(ji茅)妲�(g貌u)

    妾㈡脯鍎�涓昏鐢变綆澹撶传澶栫噲锛屽厜娉㈤亷婵惧櫒銆佸叆灏勭传澶栧厜鍙嶅皠鍣�銆佽嚟姘у惛鏀舵睜銆佹ǎ鍝佸厜闆诲偝鎰熷櫒銆侀噰妯ｅ厜闆诲偝鎰熷櫒銆佽几鍑洪’绀�銆侀浕璺儴浠舵(g貌u)鎴愩��

涓昏鎶�琛�(sh霉)鎸囨(bi膩o)

    3.1 鍙’绀哄柈浣嶏細O3 g/m 锛宮g/ m 锛沺pm

    3.2 娓噺鑼冨湇锛�0~10 O3 g/m , 0~100 O3 g/m , 0~200 O3 g/m

    3.3 妾㈡脯妤甸檺锛�10 ppb

    3.4 椤ず搴︼細璁�鏁�(sh霉)鐨� +1 %

    3.5 杓稿叆闆绘簮锛欰C110 V/ AC220 V 50~60 HZ

    3.6 妯℃摤杓稿嚭锛�0/4~20 mA


鍎�鍣ㄦ牎婧�(zh菙n)鏂规硶

    4.1 鏍℃簴(zh菙n)鍎�鍣ㄦ牎婧�(zh菙n)

    閲囩敤寰峰湅瀹夋�濈緟鏂叕鍙窯M鈥擯RO妯�(bi膩o)婧�(zh菙n)鑷哀妾㈡脯鍎�灏�(du矛)宸茬敓鐢�(ch菐n)鐨勮嚟姘ф娓剙閫�(j矛n)琛屽垎甯冮伕鍙�10鍊�(g猫)娓│榛�(di菐n)灏�(du矛)姣�锛岃宸寖鍦嶆帶鍒跺湪+1 %浠ュ収(n猫i)鐐哄悎鏍�銆�

    4.2鍖栧(xu茅)婊村畾娉�

    鍖栧(xu茅)鏂规硶鍗崇鍖栭墍銆佺～浠ｇ～閰搁垑婊村畾娉曚締妾㈡脯鑷哀婵冨害銆傛垜鍊戜篃鍒嗗竷閬稿彇10鍊�(g猫)娓│榛�(di菐n)锛岀劧鍚庣敤鑷哀妾㈡脯鍎�鑸囧寲瀛�(xu茅)婊村畾娉曟脯瑭︾殑10鍊�(g猫)榛�(di菐n)閫�(j矛n)琛屽皪(du矛)姣旓紝瑾ゅ樊鑼冨湇鎺у埗鍦� +1%浠ュ収(n猫i)銆傜鍖栭墍婊村畾娉曞師鐞嗘槸鐢ㄥ挤(qi谩ng)姘у寲鍔戣嚟姘ц垏纰樺寲閴�鍙嶆噳(y墨ng),浣跨娓搁洟鍑轰締鍒版按閲岋紝姘村氨鏈�(hu矛)璁�?y艒u)妞存灜?銆傦紙鍙�?y墨ng)寮忥細 O3+2KI+H2O O2+I2+KOH锛夊埄鐢ㄧ～浠ｇ～閰搁垑妯�(bi膩o)婧�(zh菙n)娑叉淮瀹�锛屼娇娓搁洟纰樿畩?y艒u)姒堥ィ顖梒锛屽弽鎳�(y墨ng)绲傞粸(di菐n)鐐烘按瀹屽叏瑜壊銆傦紙鍙嶆噳(y墨ng)寮忥細I2+2Na2S2O3 2NaI+Na2S4O6锛塠1]

    鑷哀婵冨害锛欳= (Ana脳B脳2400) / V0 鍠綅 (mg/l)

    (娉ㄩ噵锛欰na----纭唬纭吀閳夋(bi膩o)婧�(zh菙n)婧舵恫鐢ㄩ噺ml 锛� B---纭唬纭吀閳夋(bi膩o)婧�(zh菙n)婧舵恫婵冨害mol/l锛�

    V0-----鑷哀姘у寲鍏朵粬鍙栨ǎ楂旂⿳ml )

    5锛� 鑷哀妾㈡脯鍎�

    绲�(ji茅)璜�

    鏈枃鐮斿埗鐨勮嚟姘ф娓剙閲囩敤浜嗙传澶栫窔鍚告敹娉�锛屽柈榛�(di菐n)鍏夋簮銆侀洐鍏夎矾妾㈡脯銆侀珨绌嶅皬銆佸害楂�銆佺┅(w臎n)瀹氭�уソ銆佸彲浠ラ�ｇ簩(x霉)宸ヤ綔锛涘叾娓噺鑼冨湇瀵�锛屽ぇ娓噺鑼冨湇300 O3 g/m銆傚彟澶�锛岃┎妾㈡脯鍎�閭勫叿鏈�0/4鈥�20 mA妯℃摤杓稿嚭锛屽彲浠ヨ垏鑷哀鐧�(f膩)鐢熷櫒锛孭ID瑾�(di脿o)绡�(ji茅)鍣ㄧ祫鎴愯嚟姘ч枆鐠�(hu谩n)鑷嫊(d貌ng)鎺у埗绯荤当(t菕ng)銆�

    鍙冭�冩枃鐛�(xi脿n)锛�

    1锛庛�奌ANDBOOK OF OZONE TECHNOLOGY AND APPLICATIONS銆婻ICE锛孯IPG锛孨ETZER ANN ARBIR SCIENCE锛�1982

    2锛庛�婂湅澶栬嚟姘ф妧琛�(sh霉)鍙婃噳(y墨ng)鐢ㄦ墜鍐�(c猫)銆� 寰峰湅瀹夋�濈緟鏂叕鍙� 鐜嬭(w猫i)锛�1991


缍韩闆诲瓙閫�锛岄浕瀛愮煡璀�(sh铆)锛屼竴鏌ョ櫨閫氾紒

宸叉敹閷勮姊�168647鍊�(g猫)