1锛� 鑷�姘ф績搴︽�㈡脯(c猫)鍎� 渚�(l谩i)鑷�寰峰��(gu贸)瀹夋�濈緟鏂�鍏�鍙稿熀鏈�鍘熺��

    1.1妾㈡脯(c猫)鍘熺悊

    鎴戝�戠煡閬撳湴鐞冨ぇ姘ｅ堡涓婃湁涓�灞よ嚟姘у堡锛岀�戝��(xu茅)瀹跺�戝凡缍�(j墨ng)鐧�(f膩)鐝�(xi脿n)鑷�姘у堡鑳藉惛鏀剁传澶栫窔锛岀爺绌惰〃鏄庤嚟姘у儏灏�(du矛)娉㈤暦(zh菐ng)253.7nm鐨勭传澶栫窔鍏锋湁澶у惛鏀剁郴鏁�(sh霉)锛屽湪姝ゆ尝闀�(zh菐ng)涓嬬传澶栫窔閫氶亷(gu貌)鑷�姘ф��(hu矛)鐢�(ch菐n)鐢熻“娓�锛岀�﹀悎铇�娉㈢壒鈥斺�旀瘮鐖惧畾寰嬨�傝┎鏂规硶宸茶��缇庡湅(gu贸)绛夊湅(gu贸)瀹朵綔鐐鸿嚟姘ф��(bi膩o)婧�(zh菙n)鍒嗘瀽鏂规硶銆傝┎鑷�姘ф�㈡脯(c猫)鍎�灏辨槸閲囩敤绱�澶栫窔鍚告敹娉曠殑鍘熺悊锛岀敤绌�(w臎n)瀹氱殑绱�澶栫噲鍏夋簮鐢�(ch菐n)鐢熺传澶栫窔锛岀敤鍏夋尝閬�(gu貌)婵惧櫒閬�(gu貌)婵炬帀鍏跺畠娉㈤暦(zh菐ng)绱�澶栧��锛屽彧鍏佽ū娉㈤暦(zh菐ng)253.7nm閫氶亷(gu貌)銆傜稉(j墨ng)閬�(gu貌)妯ｅ搧鍏夐浕鍌虫劅鍣�锛屽啀缍�(j墨ng)閬�(gu貌)鑷�姘у惛鏀舵睜鍚庯紝鍒伴��(d谩)閲囨ǎ鍏夐浕鍌虫劅鍣�銆傞�氶亷(gu貌)妯ｅ搧鍏夐浕鍌虫劅鍣ㄥ拰閲囨ǎ鍏夐浕鍌虫劅鍣ㄩ浕淇¤櫉(h脿o)姣旇純锛屽啀缍�(j墨ng)閬�(gu貌)鏁�(sh霉)瀛�(xu茅)妯″瀷鐨勮▓(j矛)绠楋紝灏辫兘寰楀嚭鑷�姘ф績搴﹀ぇ灏�銆�

    1.2鑷�姘ф績搴︽�㈡脯(c猫)鍎�

    婵冨害鏁�(sh霉)瀛�(xu茅)瑷�(j矛)绠楁ā鍨�

    鑷�姘ф績搴︽��(sh霉)瀛�(xu茅)妯″瀷锛堝�傚叕寮忎竴锛夋槸鏍规摎(j霉)Lambert and Beer瀹氬緥鎺ㄥ嚭鐨勩��

    -ln I/I0

    C = 鈥斺�斺�斺�斺��

    E脳D 锛� 鍏�寮忎竴 锛�

    锛堟敞閲嬶細C-----鑷�姘ф績搴�锛屽柈浣峠 /m锛汦------ 甯告暩(sh霉)锛汥-------鑷�姘у惛鏀舵睜璺濋��锛�

    I0---------妯ｅ搧闆绘祦锛汭------閲囨ǎ闆绘祦锛�

    鍦ㄩ�欏��(g猫)鑷�姘ф績搴﹁��(j矛)绠楀叕寮忎腑锛屽彧瑕佺煡閬撴ǎ鍝侀浕娴併�侀噰妯ｉ浕娴佸拰鑷�姘у惛鏀舵睜璺濋洟锛岄偅涔堟垜鍊戝氨鍙�浠ヨ��(j矛)绠楀嚭鑷�姘ф績搴﹀ぇ灏�銆傜敱浜庯紝鑷�姘у惛鏀舵睜鐨勮窛闆㈢殑闄愬��锛屽ぇ鑷�姘ф績搴﹀彧鑳芥��(c猫)鍒�300 O3 g/m銆�

    1.3闆昏矾鍘熺悊鐨勫��(sh铆)鐝�(xi脿n)

    鍩烘湰闆昏矾鐢遍浕婧愰儴鍒�銆佺传澶栫噲鎺у埗銆佺传澶栧厜绶氭ǎ鍝佹�㈡��(c猫)銆佺传澶栧厜绶氶噰妯ｆ�㈡��(c猫)锛屽皪(du矛)鏁�(sh霉)鏀惧ぇ鍣↙og100銆佹ā鎿�杓稿嚭鍙婇’绀哄叚澶ч儴鍒嗙祫鎴�銆�

    闆昏矾鏍稿績閮ㄥ垎灏辨槸鐢ㄥ皪(du矛)鏁�(sh霉)鏀惧ぇ鍣↙og100渚�(l谩i)瀵�(sh铆)鐝�(xi脿n)鑷�姘ф績搴︽��(sh霉)瀛�(xu茅)妯″瀷銆侺OG100鏄� 14寮曡叧鍙�浠ュ��(du矛)鍏╁��(g猫)闆绘祦鎴栭浕澹撲箣姣旈��(j矛n)琛屽皪(du矛)鏁�(sh霉)閬�(y霉n)绠楃殑闆嗘垚闆昏矾锛岃┎鏀惧ぇ鍣ㄨ几鍑洪浕娴佸嫊(d貌ng)鎱�(t脿i)鑼冨湇瀵�锛屽彲浠ュ��1nA鍒� 1mA涔嬮枔璁婂寲銆傝几鍑鸿�ゅ樊鑼冨湇涓�0.1%?锛涱姠绐樻吵鈧�锛堝�傚湒1锛� 锛岃几鍑哄叕寮忥細 Vout =VT脳ln I0/I (娉ㄩ噵锛歏T---甯告暩(sh霉)锛沄out---杓稿嚭闆诲��)銆�

    闆绘簮閮ㄥ垎涓昏�佹槸鐢�(ch菐n)鐢熺传澶栫噲闇�瑕佺殑楂樺�撻浕婧�锛屽悓鏅�(sh铆)鐢�(ch菐n)鐢熼浕璺�鏉夸笂闇�瑕佺殑+15V鐩存祦闆汇�傜传澶栫噲鐕堟帶閮ㄥ垎涓昏�佹槸鎺у埗绱�澶栫噲鐕堥浕娴佸湪鎭掑畾鍏佽ū鑼冨湇涔嬪収(n猫i)锛岄亷(gu貌)楂�銆侀亷(gu貌)浣庡彲浠ヨ嚜鍕�(d貌ng)瑾�(di脿o)绡�(ji茅)锛屽�傛灉瑾�(di脿o)涓嶄簡瑾�(shu艒)鏄庣传澶栫噲澹藉懡鍒颁簡锛岄潰鏉夸笂鏈変竴鍊�(g猫)绱呯噲璁婁寒锛屾彁绀轰綘鎳�(y墨ng)瑭叉洿鎻涙柊鐨勭传澶栫噲浜�銆傛��(bi膩o)婧�(zh菙n)绱�澶栧厜妾㈡��(c猫)鍜岄噰妯ｇ传澶栧厜妾㈡脯(c猫)閮ㄥ垎涔熸槸杓冮棞(gu膩n)閸甸儴鍒�锛�.鍏夐浕鍌虫劅鍣ㄦ妸绱�澶栫窔鐨勫厜淇¤��(h脿o)杞�(zhu菐n)鎻涚偤闆诲�撲俊铏�(h脿o)锛岀劧鍚庣稉(j墨ng)鍏╂�￠��(y霉n)绠楁斁澶у櫒閫�(j矛n)琛屼俊铏�(h脿o)鏁寸悊鏀惧ぇ锛岄�佺郸LOG100閫�(j矛n)琛岃▓(j矛)绠楄檿鐞嗗悗锛岄’绀鸿几鍑�銆傛ā鎿�杓稿��0~20mA鑸囪嚟姘ф績搴﹀ぇ灏忔槸鎴愮窔鎬ч棞(gu膩n)绯荤殑銆�

    鑷�姘ф績搴︽�㈡脯(c猫)鍎�鏁存��(j墨)楂旂�嶅��锛岄珮绮惧害銆侀珮鍒嗚鲸鐜�锛岄熆鎳�(y墨ng)杩呴��锛涜嚟姘ф績搴︽�㈡��(c猫)鍎�閲囩敤澶у�归噺鍙�鍏呴浕閶伴浕姹狅紝鍙�闀�(zh菐ng)鏅�(sh铆)闁撻�ｇ簩(x霉)宸ヤ綔锛屽叿鏈夋檪(sh铆)闁撻’绀�锛屽墿浣欓浕閲忛’绀哄姛鑳�锛屾暩(sh霉)瀛桳CD鑳屽厜椤�绀�锛岄’绀烘脯(c猫)瑭︽埃楂�锛屽柈浣�锛屾车鍚搁’绀�锛涜伈鍏夈�佹尟鍕�(d貌ng)鍫�(b脿o)璀﹀姛鑳�銆侀浕姹犱綆闆婚噺鍫�(b脿o)璀︺�佸偝鎰熷櫒鏁呴殰妾㈡脯(c猫)鍫�(b脿o)璀﹀姛鑳借秴閲忕▼鍫�(b脿o)璀�锛涜嚟姘ф績搴︽�㈡��(c猫)鍎�鍌虫劅鍣ㄩ噰鐢ㄥ師瑁濋��(j矛n)鍙ｉ浕鍖栧��(xu茅)鍌虫劅鍣�锛屼��銆佷笅闄愬牨(b脿o)璀﹀�煎彲浠绘剰瑷�(sh猫)瀹�锛岃嚜甯堕浂榛�(di菐n)鍜岀洰妯�(bi膩o)榛�(di菐n)鏍℃簴(zh菙n)鍔熻兘锛涜嚟姘ф績搴︽�㈡��(c猫)鍎�鍏�(n猫i)缃�婧�搴﹁��(b菙)鍎燂紝娓涘皬娓�(c猫)閲忚�ゅ��锛岀董璀�(h霉)鏂逛究锛屾暩(sh霉)鎿�(j霉)鎭㈠京(f霉)鍔熻兘锛屽厤鍘昏�ゆ搷浣滃紩璧风殑鍚庨¨涔嬫��锛屽�栨�奸噰鐢ㄧ壒娈婃潗璩�(zh矛)鍙婂伐钘濓紝涓嶆槗纾ㄦ悕锛屾槗娓呮綌锛岄暦(zh菐ng)鏅�(sh铆)闁撲娇鐢ㄥ厜浜�濡傛��銆�

    2锛� 鑷�姘ф績搴︽�㈡脯(c猫)鍎�

    鍩烘湰 绲�(ji茅)妲�(g貌u)

    妾㈡脯(c猫)鍎�涓昏�佺敱浣庡�撶传澶栫噲锛屽厜娉㈤亷(gu貌)婵惧櫒銆佸叆灏勭传澶栧厜鍙嶅皠鍣�銆佽嚟姘у惛鏀舵睜銆佹ǎ鍝佸厜闆诲偝鎰熷櫒銆侀噰妯ｅ厜闆诲偝鎰熷櫒銆佽几鍑洪’绀�銆侀浕璺�閮ㄤ欢妲�(g貌u)鎴�銆�(濡傚湒2)

    3锛� 涓昏�佹妧琛�(sh霉)鎸囨��(bi膩o)

    3.1 鍙�椤�绀哄柈浣嶏細O3 g/m 锛宮g/ m 锛沺pm

    3.2 娓�(c猫)閲忚寖鍦嶏細0~10 O3 g/m , 0~100 O3 g/m , 0~200 O3 g/m

    3.3 妾㈡脯(c猫)妤甸檺锛�10 ppb

    3.4 椤�绀哄害锛氳畝鏁�(sh霉)鐨� +1 %

    3.5 杓稿叆闆绘簮锛欰C110 V/ AC220 V 50~60 HZ

    3.6 妯℃摤杓稿嚭锛�0/4~20 mA

    4锛庡剙鍣ㄦ牎婧�(zh菙n)鏂规硶

    4.1 鏍℃簴(zh菙n)鍎�鍣ㄦ牎婧�(zh菙n)

    閲囩敤寰峰湅(gu贸)瀹夋�濈緟鏂�鍏�鍙窯M鈥擯RO妯�(bi膩o)婧�(zh菙n)鑷�姘ф�㈡脯(c猫)鍎�灏�(du矛)宸茬敓鐢�(ch菐n)鐨勮嚟姘ф�㈡��(c猫)鍎�閫�(j矛n)琛屽垎甯冮伕鍙�10鍊�(g猫)娓�(c猫)瑭﹂粸(di菐n)灏�(du矛)姣旓紝瑾ゅ樊鑼冨湇鎺у埗鍦�+1 %浠ュ収(n猫i)鐐哄悎鏍�銆�

    4.2鍖栧��(xu茅)婊村畾娉�

    鍖栧��(xu茅)鏂规硶鍗崇�樺寲閴�銆佺～浠ｇ～閰搁垑婊村畾娉曚締(l谩i)妾㈡脯(c猫)鑷�姘ф績搴︺�傛垜鍊戜篃鍒嗗竷閬稿彇10鍊�(g猫)娓�(c猫)瑭﹂粸(di菐n)锛岀劧鍚庣敤鑷�姘ф�㈡脯(c猫)鍎�鑸囧寲瀛�(xu茅)婊村畾娉曟脯(c猫)瑭︾殑10鍊�(g猫)榛�(di菐n)閫�(j矛n)琛屽皪(du矛)姣旓紝瑾ゅ樊鑼冨湇鎺у埗鍦� +1%浠ュ収(n猫i)銆傜�樺寲閴�婊村畾娉曞師鐞嗘槸鐢ㄥ挤(qi谩ng)姘у寲鍔戣嚟姘ц垏纰樺寲閴�鍙嶆噳(y墨ng),浣跨�樻父闆㈠嚭渚�(l谩i)鍒版按閲�锛屾按灏辨渻(hu矛)璁�?y艒u)妞存灜顏烇純菤纾�?y墨ng)寮忥細 O3+2KI+H2O O2+I2+KOH锛夊埄鐢ㄧ～浠ｇ～閰搁垑妯�(bi膩o)婧�(zh菙n)娑叉淮瀹�锛屼娇娓搁洟纰樿畩?y艒u)姒堥ィ顖梒锛屽弽鎳�(y墨ng)绲傞粸(di菐n)鐐烘按瀹屽叏瑜�鑹�銆傦紙鍙嶆噳(y墨ng)寮忥細I2+2Na2S2O3 2NaI+Na2S4O6锛�

    鑷�姘ф績搴︼細C= (Ana脳B脳2400) / V0 鍠�浣� (mg/l)

    (娉ㄩ噵锛欰na----纭�浠ｇ～閰搁垑妯�(bi膩o)婧�(zh菙n)婧舵恫鐢ㄩ噺ml 锛� B---纭�浠ｇ～閰搁垑妯�(bi膩o)婧�(zh菙n)婧舵恫婵冨害mol/l锛�

    V0-----鑷�姘ф哀鍖栧叾浠栧彇妯ｉ珨绌峬l )

    5锛� 鑷�姘ф績搴︽�㈡脯(c猫)鍎�

    绲�(ji茅)璜�

    鏈�鏂囩爺鍒剁殑鑷�姘ф績搴︽�㈡��(c猫)鍎�閲囩敤浜嗙传澶栫窔鍚告敹娉曪紝鍠�榛�(di菐n)鍏夋簮銆侀洐鍏夎矾妾㈡脯(c猫)銆侀珨绌嶅皬銆佸害楂�銆佺┅(w臎n)瀹氭�уソ銆佸彲浠ラ�ｇ簩(x霉)宸ヤ綔锛涘叾娓�(c猫)閲忚寖鍦嶅��锛屽ぇ娓�(c猫)閲忚寖鍦�300 O3 g/m銆傚彟澶栵紝瑭叉�㈡��(c猫)鍎�閭勫叿鏈�0/4鈥�20 mA妯℃摤杓稿嚭锛屽彲浠ヨ垏鑷�姘х��(f膩)鐢熷櫒锛孭ID瑾�(di脿o)绡�(ji茅)鍣ㄧ祫鎴愯嚟姘ч枆鐠�(hu谩n)鑷�鍕�(d貌ng)鎺у埗绯荤当(t菕ng)銆�

    鍙冭�冩枃鐛�(xi脿n)锛�

    1锛庛�奌ANDBOOK OF OZONE TECHNOLOGY AND APPLICATIONS銆婻ICE锛孯IPG锛孨ETZER ANN ARBIR SCIENCE锛�1982

    2锛庛�婂湅(gu贸)澶栬嚟姘ф妧琛�(sh霉)鍙婃噳(y墨ng)鐢ㄦ墜鍐�(c猫)銆� 寰峰湅(gu贸)瀹夋�濈緟鏂�鍏�鍙�锛� 鐜嬭��(w猫i) 锛�1991