銆�銆�1911骞�锛岃嵎铇瀛�(xu茅)瀹�?锛熸仌銇燁煂鈹濆抚銇愮皾?n猫i)鏂敤娑叉唉鍐峰嵒姹�锛岀暥(d膩ng)婧害涓嬮檷鍒版韩妯�(bi膩o)4.2K鏅�(sh铆)姘撮妧鐨勯浕闃诲畬鍏ㄦ秷澶�锛岄�欑ó鐝�(xi脿n)璞＄ū鐐鸿秴灏�(d菐o)闆绘��锛屾婧害绋辩偤鑷ㄧ晫婧害銆傛牴鎿�(j霉)鑷ㄧ晫婧害鐨勪笉鍚�锛岃秴灏�(d菐o)鏉愭枡鍙互琚垎鐐猴細楂樻韩瓒呭皫(d菐o)鏉愭枡鍜屼綆婧秴灏�(d菐o)鏉愭枡銆備絾閫欓噷鎵�瑾�(shu艒)鐨勩�岄珮婧��锛屽叾瀵�(sh铆)浠嶇劧鏄仩(yu菐n)浣庢柤鍐伴粸(di菐n)鏀濇皬0鈩冪殑锛屽皪(du矛)涓�鑸汉渚�(l谩i)瑾�(shu艒)绠楁槸妤典綆鐨勬韩搴�銆�
銆�銆�1933骞�锛岄倎鏂磵鍜屽ェ鍏嬫．鑿茬埦寰峰叐浣嶇瀛�(xu茅)瀹剁櫦(f膩)鐝�(xi脿n)锛屽鏋滄妸瓒呭皫(d菐o)楂旀斁鍦ㄧ鍫�(ch菐ng)涓喎鍗�锛屽墖鍦ㄦ潗鏂欓浕闃绘秷澶辩殑鍚屾檪(sh铆)锛岀鎰熸噳(y墨ng)绶氬皣寰炶秴灏�(d菐o)楂斾腑鎺掑嚭锛屼笉鑳介�氶亷(gu貌)瓒呭皫(d菐o)楂�锛岄�欑ó鐝�(xi脿n)璞＄ū鐐烘姉纾佹��銆�
銆�銆�缍�(j墨ng)閬�(gu貌)绉戝(xu茅)瀹跺�戠殑鍔姏锛岃秴灏�(d菐o)鏉愭枡鐨勭闆婚殰绀欏凡琚法瓒�锛屼笅涓�鍊�(g猫)闆ｉ棞(gu膩n)鏄獊鐮存韩搴﹂殰绀�锛屽嵆灏嬫眰楂樻韩瓒呭皫(d菐o)鏉愭枡銆�
銆�銆�1973骞达紝鐧�(f膩)鐝�(xi脿n)瓒呭皫(d菐o)鍚堥噾鈥曗�曢埉閸哄悎閲�锛屽叾鑷ㄧ晫瓒呭皫(d菐o)婧害鐐�23.2K锛岄�欎竴瑷橀寗淇濇寔浜嗚繎13骞�銆�
銆�銆�1986骞达紝瑷�(sh猫)鍦ㄧ憺澹槆榛庝笘鐨勭編鍦�(gu贸)IBM鍏徃鐨勭爺绌朵腑蹇冨牨(b脿o)閬撲簡涓�绋哀鍖栫墿锛堥懎閶囬妳姘у寲鐗╋級鍏锋湁35K鐨勯珮婧秴灏�(d菐o)鎬�銆傛鍚庯紝绉戝(xu茅)瀹跺�戝咕涔庢瘡闅斿咕澶�锛屽氨鏈夋柊鐨勭爺绌舵垚鏋滃嚭鐝�(xi脿n)銆�
銆�銆�1986骞达紝缇庡湅(gu贸)璨濈埦瀵�(sh铆)椹�(y脿n)瀹ょ爺绌剁殑瓒呭皫(d菐o)鏉愭枡锛屽叾鑷ㄧ晫瓒呭皫(d菐o)婧害閬�(d谩)鍒�40K锛屾恫姘殑鈥滄韩搴﹀澹樷�濓紙40K锛夎璺ㄨ秺銆�
銆�銆�1987骞达紝涓湅(gu贸)绉戝(xu茅)瀹惰稒蹇犺尝浠ュ強缇庡湅(gu贸)鑿绉戝(xu茅)瀹舵湵缍�(j墨ng)姝︾浉绻煎湪閲旓紞閶囷紞閵咃紞姘х郴鏉愭枡涓婃妸鑷ㄧ晫瓒呭皫(d菐o)婧害鎻愰珮鍒�90K浠ヤ笂锛屾恫姘殑鈥滄韩搴﹀澹樷�濓紙77K锛変篃琚獊鐮翠簡銆�1987骞村簳锛岄増锛嶉媷锛嶉垼锛嶉妳锛嶆哀绯绘潗鏂欏張鎶婅嚚鐣岃秴灏�(d菐o)婧害鐨勮閷勬彁楂樺埌125K銆傚緸1986锛�1987骞寸殑鐭煭涓�骞村鐨勬檪(sh铆)闁撻噷锛岃嚚鐣岃秴灏�(d菐o)婧害鎻愰珮浜嗚繎100K銆�
銆�銆�2001骞达紝浜岀〖鍖栭巶锛圡gB2锛夎鐧�(f膩)鐝�(xi脿n)鍏惰秴灏�(d菐o)鑷ㄧ晫婧害閬�(d谩)鍒�39K [1]銆傛鍖栧悎鐗╃殑鐧�(f膩)鐝�(xi脿n)锛屾墦鐮翠簡闈為妳姘у寲鐗╄秴灏�(d菐o)楂旓紙non-cuprate superconductor锛夌殑鑷ㄧ晫婧害绱�(j矛)閷�銆�
銆�銆�1990鑷�2000骞翠唬锛屽叿ZrCuAsSi绲�(ji茅)妲�(g貌u)鐨勭█鍦熼亷(gu貌)娓￠噾灞爱纾锋棌鍖栧悎鐗╋紙rare-earth transition-metal oxypnictide, ReTmPnO锛夐櫢绾�(x霉)琚櫦(f膩)鐝�(xi脿n)[2] [3]銆備絾骞舵湭鏈変汉鐧�(f膩)鐝�(xi脿n)鍏朵腑鐨勮秴灏�(d菐o)鐝�(xi脿n)璞�銆�
銆�銆�2008骞�锛屾棩鏈殑Hideo Hosono鍦�(tu谩n)闅�(du矛)鐧�(f膩)鐝�(xi脿n)鍦ㄩ惖鍩烘爱纾锋棌姘у寲鐗╋紙iron-based oxypnictide涓�锛屽皣閮ㄤ唤姘т互鎽婚洔鐨勬柟寮忕敤姘熶綔閮ㄤ唤鍙栦唬锛屽彲浣縇aFeAsO1-xFx鐨勮嚚鐣屾韩搴﹂仈(d谩)鍒�26K[4]锛屽湪鍔犲寰岋紙4 GPa锛夌敋鑷冲彲閬�(d谩)鍒�43K[5]銆傚叾寰�锛屼腑鍦�(gu贸)鐨勮仦?锛涱暛F(tu谩n)闅�(du矛)锛岀櫦(f膩)鐝�(xi脿n)鍦ㄤ互閸跺彇浠ｇ█鍦熷厓绱犱箣寰�锛孡a1-xSrxFeAsO浜﹀彲閬�(d谩)鍒拌嚚鐣屾韩搴�25K[6]銆傚叾寰�锛屼腑鍦�(gu贸)鐨勭瀛�(xu茅)瀹堕櫝浠欒紳銆佽稒蹇犺尝绛変汉锛岀櫦(f膩)鐝�(xi脿n)灏囬懎浠ュ叾浠栫█鍦熷厓绱犱綔鍙栦唬锛屽墖鍙緱鍒版洿楂樼殑鑷ㄧ晫婧害锛涘叾涓紝SmFeAs[O0.9F0.1]鍙仈(d谩)55K[7] [8]銆傚彟澶栵紝灏囬惖浠ラ埛鍙栦唬锛圠aFe1-xCoxAsO锛�锛岀█鍦熷厓绱犱互閲峰彇浠ｏ紙Gd1-xThxFeAsO锛�锛屾垨鏄埄鐢ㄦ哀缂洪櫡锛圠aFeAsO1-未锛夌瓑鏂瑰紡锛屼篃閮藉彲浠ュ紩鐧�(f膩)瓒呭皫(d菐o)[9] [10] [11]銆�
銆�銆�姝ょ郴绲�(t菕ng)浜﹁绨�(ji菐n)绋辩偤銆�1111绯荤当(t菕ng)銆�銆傛鍖栧悎鐗╃殑鐧�(f膩)鐝�(xi脿n)锛岄潪浣嗗啀搴︽墦鐮翠簡鐢盡gB2淇濇寔鐨勯潪閵呮哀鍖栫墿瓒呭皫(d菐o)楂旓紙non-cuprate superconductor锛夌殑鑷ㄧ晫婧害绱�(j矛)閷�锛屽叾鍚惖鍗绘湁瓒呭皫(d菐o)鐨勭壒鎬т篃鍙椾汉娉ㄧ洰銆�
銆�銆�鍚屾ǎ鍦�2008骞达紝鍙楀埌涓婅堪銆�1111绯荤当(t菕ng)銆嶇殑鍟熺櫦(f膩)锛孴hCr2Si2绲�(ji茅)妲�(g貌u)鐨勯辜鍦熼噾灞爱纾锋棌鍖栧悎鐗╋紙ATm2Pn2锛変害琚櫦(f膩)鐝�(xi脿n)锛屽湪灏嘊aFe2As2涓皣楣煎湡閲戝爆锛圛IA锛変互楣奸噾灞紙IA锛夐儴鍒嗗彇浠�锛屼害鍙緱鍒拌嚚鐣屾韩搴︾磩30鑷�40K鐨勯珮婧秴灏�(d菐o)楂�锛屽Ba1-xKxFe2As2锛�38 K锛� [12]銆傛绯荤当(t菕ng)浜﹁绨�(ji菐n)绋辩偤銆�122绯荤当(t菕ng)銆�銆傚鍚屾哀鍖栫墿瓒呭皫(d菐o)楂�锛屻��1111銆嶈垏銆�122銆嶇郴绲�(t菕ng)鐨勮秴灏�(d菐o)渚�(l谩i)婧愪篃鏄敱灞ょ媭绲�(ji茅)妲�(g貌u)涓殑FeAs灞よ并鐛�(xi脿n)锛岃棄鐢变笉鍚屽児(ji脿)鏁�(sh霉)鐨勯洟瀛愭懟闆滄垨鏄哀缂洪櫡锛屽彲鎻愬崌FeAs灞よ級瀛愮殑婵冨害锛岄��(j矛n)鑰屽紩鐧�(f膩)瓒呭皫(d菐o)銆�
